Reduction of Aromatic Ketones in an Aluminum Chloride: Dialkylimidazolium Chloride Molten Salt System
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چکیده
منابع مشابه
Molten Triazolium Chloride Systems as New Aluminum Battery Electrolytes
The possibility of using molten mixtures of 1,4-dimethyl-l,2,4-triazolium chloride (DMTC) and aluminum chloride (A1C13) as secondary battery electrolytes was studied, in some cases extended by the copresence of sodium chloride. DMTC-A1CI~ mixtures demonstrated high specific conductivity in a wide temperature range. The equimolar system is most conductive and has K values between 4.02 x 10 -~ an...
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Chronopotent iometry of chromate in the presence of NiC12 in molten LiCIKCI eutectic reveals a diffusion controlled, three electron reduct ion step. In the presence of excess NiC12, chromate is reduced at --0.35V vs. P t ( I I ) / P t reference electrode and the electroactive species responsible for the chronopotentiometric wave is estimated to have a diffusion coefficient of 1.06 9 10 -5 cm 2 ...
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The dependence of indium electro de potential vs. log. concentration of indium (III) is linear and the slopes determined are comparable with the slopes calculated from the Nernst equation, assuming n = 3. The potential of In/ln(III) has been determined to be 0.805 ± 0.003 V with respect to Pt/PtC12 (1 M). At 693 K the free energy of formation of the indium(III) chloride in a 1 M solution is -32...
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Molybdenum(VI) oxide reacts with molten LiC1-KCI eutectie at 450 ~ to form MOO2C12, which probably is present as an anion MoO2Cl4 =, and pyromolybdate, Mo207 =. Both of these species are electrochemically reduced to MOO2, which can be reoxidized to MoO2CI2 by current reversal. A second reduction step, observed whether MoO3 or Mo2072is added to the melt, can be attributed to the reduction of MoO...
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ژورنال
عنوان ژورنال: ECS Proceedings Volumes
سال: 1984
ISSN: 0161-6374,2576-1579
DOI: 10.1149/198402.0163pv